Naphthalene-a-sulfonate, S-Benzylthiuronium Naphthalene-α-sulfonate and S-Benzylthiuronium Naphthalene-β-sulfonate.

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Phenyl naphthalene-2-sulfonate

In the crystal structure of the title compound, C(16)H(12)O(3)S, the dihedral angle between the naphthalene ring system and the phenyl ring is 65.21 (3)°. The mol-ecules are linked by inter-molecular C-H⋯O hydrogen bonds, forming a chain along the a axis. The chains are connected through weak C-H⋯π inter-actions.

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In the crystal structure of the title compound, C(16)H(11)NO(5)S, the plane of the naphthalene ring system forms a dihedral angle of 63.39 (8)° with the benzene ring. The nitro group makes a dihedral angle of 10.73 (16)° with the benzene ring. Weak intra- and inter-molecular C-H⋯O inter-actions are observed.

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In the title compound, C(16)H(13)NO(3)S, the plane of the amino-benzene ring makes a dihedral angle of 61.04 (6)° with the naphthalene ring system. Both ring systems form weak intra-molecular C-H⋯O hydrogen bonds with the sulfonate group. In the crystal structure, weak inter-molecular N-H⋯O hydrogen bonds and a C-H⋯π inter-action are observed.

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ژورنال

عنوان ژورنال: The Journal of the Society of Chemical Industry, Japan

سال: 1956

ISSN: 0023-2734,2185-0860

DOI: 10.1246/nikkashi1898.59.463